Nanoporous palladium catalyst for the reduction of aromatic nitro compounds with silane/alcohol system as the hydrogen source

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作者单位: Taishan Med Univ, Sch Chem & Pharmaceut Engn, Tai An 271016, Shandong, Peoples R China Shandong First Medical University & Shandong Academy of Medical Sciences

关键词: CHEMOSELECTIVE HYDROGENATION GOLD NANOPARTICLES NITROARENES ORGANOSILANES OXIDATION EFFICIENT ETHYLENE CARBON

摘要: Graphical abstract Reduction of aromatic nitro compounds to aromatic amines was realized with excellent yield by using nanoporous palladium as sustainable catalyst and silane/alcohol as hydrogen source. Unlabelled Image Highlights • Np-Pd/hydrosilanes/alcohol system was used for hydrogen transfer reaction. • The reduction of aromatic nitro to prepare aromatic amines was realized with green hydrogen source. • A possible mechanism was proposed with kinetic studies.

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