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作者单位

Taishan Med Univ, Sch Chem & Pharmaceut Engn, Tai An 271016, Shandong, Peoples R China Shandong First Medical University & Shandong Academy of Medical Sciences

刊名

INORGANIC CHEMISTRY COMMUNICATIONS

年份

2019

卷号

Vol.100

页码

1-5

ISSN

1387-7003

关键词

CHEMOSELECTIVE HYDROGENATION GOLD NANOPARTICLES NITROARENES ORGANOSILANES OXIDATION EFFICIENT ETHYLENE CARBON

摘要

Graphical abstract Reduction of aromatic nitro compounds to aromatic amines was realized with excellent yield by using nanoporous palladium as sustainable catalyst and silane/alcohol as hydrogen source. Unlabelled Image Highlights • Np-Pd/hydrosilanes/alcohol system was used for hydrogen transfer reaction. • The reduction of aromatic nitro to prepare aromatic amines was realized with green hydrogen source. • A possible mechanism was proposed with kinetic studies.

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