Chromatography is one of the most used techniques for complex sample analysis, and the preparation of high-performance stationary phases is the key to its advancement. Microporous organic networks are a class of porous materials formed via Sonogashira-Hagihara coupling reactions between aromatic halides and alkynes. Owning to the high specific surface area, excellent solvent and thermal stability, tunable pore sizes, and ease of functionalization, MONs have demonstrated significant potential in ...更多
Chromatography is one of the most used techniques for complex sample analysis, and the preparation of high-performance stationary phases is the key to its advancement. Microporous organic networks are a class of porous materials formed via Sonogashira-Hagihara coupling reactions between aromatic halides and alkynes. Owning to the high specific surface area, excellent solvent and thermal stability, tunable pore sizes, and ease of functionalization, MONs have demonstrated significant potential in chromatographic separation recently. This review first briefly outlines the development history, synthesis, and functionalization strategies of MONs, then introduces the research progress of MONs as chromatographic stationary phases in high-performance liquid chromatog- raphy, gas chromatography, and capillary electrochromatography, and finally discusses the prospects and challenges of MONs in chromatography. This review will provide valuable insights for the design and application of novel MON-based chromatographic stationary phases.收起
